Aquacarbonyl(ferrocenyldithiophosphonato-κ2 S,S′)bis(triphenylphosphane-κP)ruthenium(II) dichloromethane monosolvate
نویسندگان
چکیده
The structure of the title complex, [FeRu(C5H5)(C5H4OPS2)(CO)(C18H15P)2(H2O)]·CH2Cl2, consists of one neutral [{FcP(O)S2}Ru(CO)(H2O)(PPh3)2] complex [Fc = Fe(η(5)-C5H4)(η(5)-C5H5)] and one CH2Cl2 solvent mol-ecule. The geometry around the Ru(II) atom is pseudo-octa-hedral, with two cis-binding PPh3 ligands and one chelating bidentate [Fc(O)PS2](2-) ligand via two S atoms. The average Ru-S and Ru-P bond lengths are 2.434 (1) and 2.398 (1) Å, and the Ru-O and Ru-C bond lengths are 2.157 (3) and 1.826 (4) Å, respectively. In the crystal, pairs of O-H⋯O hydrogen bonds link adjacent mol-ecules into dimers.
منابع مشابه
cis-Bis(O-methyldithiocarbonato-κ2 S,S′)bis(triphenylphosphane-κP)ruthenium(II)
In the title compound, [Ru(CH3OCS2)2(C18H15P)2], the Ru(II) atom is in a distorted octa-hedral coordination by two xanthate anions (CH3OCS2) and two tri-phenyl-phosphane (PPh3) ligands. Both bidentate xanthate ligands coordinate the Ru(II) atom with two slightly different Ru-S bond lengths but with virtually equal bite angles [71.57 (4) and 71.58 (3)°]. The packing of the complexes is assured b...
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عنوان ژورنال:
دوره 69 شماره
صفحات -
تاریخ انتشار 2013